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hca14 SM CH17 doc

Size: 600 Kb Pages: N/A Date: 2013-07-17
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hca14 SM CH17 doc
hca14 SM CH17 doc

Size: 600 Kb Pages: N/A Date: 2013-07-17

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CH17 pdf
CH17 pdf

∞ pressure of a fluid, p = nRT/V – (2πN /V ) ∫0 g ( r ) v2 r 2 dr . 2 2 kinetic pressure, the contribution to the pressure from the impact of the molecules in free flight. 17.7 Residual entropies residual entropy, a non-zero entropy at T = 0 arising from molecular disorder, SM = R ln s. equilibrium constant in terms of partition functions,  ν J  −∆ E / RT K = ∏ ( qJ,m ° / N A )  e r 0 .

Size: 1741 Kb Pages: N/A Date: 2012-12-29

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callister7e sm ch17 13a pdf
callister7e SM CH17 13a pdf

C / mol) m2 - sThe units ofR inEquation 17.23 are length/time, or in theI scheme, m/s.In order to convert the above expression to the units of m/s it is necessary to multiply r by the atomic weightA and divide by the density ρ as rA (mol / m2 - s)(g / mol) = = m/s ρ g / m3Thus, theK'AiR =Fρ in which

Size: 31 Kb Pages: 1 Date: 2013-08-15

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callister7e sm ch17 32 pdf
callister7e SM CH17 32 pdf

If the values are not the same then the other kinetic relationships need to be explored. Thus, the three equations are 1.54 = 10K3 23.24 = 150K3 95.37 = 620K3 In all three instances the value of K3 is about equal to 0.154, which means the oxidation rate obeys a linear expression.

Size: 16 Kb Pages: 1 Date: 2013-02-26

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callister7e sm ch17 23 pdf
callister7e SM CH17 23 pdf

Excerpts from this work may be reproduced by instructors for distribution on a not-for-profit basis for testing or instructional purposes only to students enrolled in courses for which the textbook has been adopted. Any other reproduction or translation of this work beyond that permitted by Sections 107 or 108 of the 1976 United States Copyright Act without the permission of the copyright owner is unlawful.

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callister7e sm ch17 31a pdf
callister7e SM CH17 31a pdf

Thus, a parabolic rate expression is not obeyed by this reaction. Let us now investigate linear kinetics in the same manner, using Equation 17.35, W = K3t. Since these K3 values are all different, a linear rate law is not a possibility, and, by process of elimination, a logarithmic expression is obeyed. (b) In order to determine the value of W after 5000 min, it is first necessary that we solve for the K4, K5, and K6 constants of Equation 17.36.

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callister7e sm ch17 15 pdf
callister7e SM CH17 15 pdf

(b) Activation polarization is rate controlling when the reaction rate is low and/or the concentration of active species in the liquid solution is high. (c) Concentration polarization is rate controlling when the reaction rate is high and/or the concentration of active species in the liquid solution is low.

Size: 13 Kb Pages: 1 Date: 2013-02-26

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ch17 doc
CH17 doc

Size: 220 Kb Pages: N/A Date: 2011-01-17

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phk9e exploring the internet stu ch17 doc
phk9e exploring the internet stu CH17 doc

Size: 34 Kb Pages: N/A Date: 2011-10-22

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tif ch17 doc
tif CH17 doc

Size: 128 Kb Pages: N/A Date: 2013-07-21

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